Here are some links you can read. The key points are using a fabric that blocks UV radiation (which isn't hard), and more importantly, using one that is breathable so that it doesn't trap moisture under the cover.
https://www.aircraftcovers.com/faqs
https://www.avweb.com/ownership/win...n-kensey-president-of-kennon-aircraft-covers/
I used a cover on a motor glider for several years and I'd been re-considering that approach recently when the hangar prospects started looking grim, with the potential for our incoming aircraft being out in the elements for at least a few months. On my motor glider, I found I needed to replace the original cover after about 5 years of full time use, but it protected the aircraft just fine. My personal experience has the caveat that this was in western South Dakota where humidity was fairly low most of the year.
Before you ask "Who did you buy it from?" I'll add that I purchased Sunbrella awning fabric and sewed it myself at the same time I sewed a camping cover for our pontoon boat. Sunbrella fabric is "water repellent", not "waterproof", because it has to stay breathable (and you may need to refresh the water repellency with some fabric guard 303 every couple years).
Sunbrella not hard to sew on a decent quality conventional sewing machine and for a Deachlon, you're doing straight pieces and seams. However, the pieces are large and the seams are long. As I recall the standard widths for Sunbrella fabric are 46" and 60". The wing cord on a Citabria or Decathlon is 64". You'll also need about 6" each to wrap around the leading and trailing edges, you'll need about 2" inches each for the hem and strap attachment, and 2 more inches for the seam on the wing. Consequently with 82" required, I'd just sew two pieces of 46" width fabric together, fold it over on one end a couple feet, sew it together to form a pocket for the wing tip, and then sew a hem on each side on the entire length and then sew the straps on to secure the cover. I used 2" nylon webbing with microfiber cloth sewn on the wing side and fastex buckles.
Rinse and repeat for the other wing and then I'd connect the two wing pieces in the middle with a canopy cover over the windshield and greenhouse. You can use some large pieces of paper (like the paper movers used to wrap things) to make a pattern. Fastex buckles on short nylon straps will let you connect the canopy cover to the wing covers and adjust the tension. If you sew the hem on the pieces 1" wide you can run 1/8" bungee cord through it to keep the edges snug in between the straps. I'd also line the canopy cover with microfiber or another soft and breathable fabric to protect the plexiglass.
I used the same Capri blue color that I used for our boat's camping cover. For a Decathlon you'd need about 16 yards for the wings and canopy cover. You should be able to get that quantity at about $20 per yard in a 46" width, so about $320 for the fabric.
With slightly more effort you can use about 7" of the extra 10" to sew sleeves for pool noodles about 1/4 of the way back on the wing's chord line to create spoilers over the wing. I used two 4 ft pool noodles per wing on my motor glider, but you could do the whole span if you wanted too. The closed cell foam in the pool noodle won't hold moisture.
The fuselage and tail covers will require a bit more effort as you'll need to work around the flying wires on the horizontal and vertical stabilizers, but you could either use zippers or velcro. You'll want a flap under the zippers to keep them off the fabric, and that requires some slightly higher level sewing skill. A velcro flap is easier, but sewing velcro requires a machine with good thread tension adjustment. I have a Juki that works great with velcro and nylon webbing that is not high end by serious sewing standards, but it still has a comma in the price.
Still, if you have access to a sewing machine you should be able to sew the covers for the whole aircraft for around $500. For another couple hundred you could probably find someone to sew it for you, if you provide the dimensions for the wing covers and paper patterns for the fail surface covers. And of course you can probably also buy covers commercially and the Decathlon is common enough that someone has probably already done the design work.